期刊
POLYMER CHEMISTRY
卷 4, 期 18, 页码 4966-4973出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py00288h
关键词
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资金
- Deutsche Forschungsgemeinschaft (DFG) [SPP 1568]
- Thuringian Ministry for Education, Science and Culture (TMBWK) [B515-10065, B514-09051, B515-11028]
- Fonds der chemischen Industrie (FCI)
- DPI (technology area HTE)
The utilization of metal ligand interactions within polymers generates materials which are of interest for several applications, including self-healing materials. In this work we use methacrylate copolymers containing terpyridine moieties in the side chain for the formation of self-healing metallopolymer networks. The materials were synthesized using the reversible addition fragmentation chain transfer (RAFT) polymerization technique and subsequent crosslinking by the addition of a metal salt, here cadmium(II) salts, with different counter-ions. The influence of the counter-ions on the self-healing process within these structures was analyzed. The research resulted in a new polymeric material featuring a high (intrinsic) healing efficiency at relatively low temperatures (<75 degrees C).
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