期刊
POLYMER CHEMISTRY
卷 4, 期 22, 页码 5570-5576出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py00745f
关键词
-
资金
- National Natural Science Foundation of China (NSFC) [21274102, 21074087]
In order to overcome the poor mechanical property of classic hydrogels, many methods have been explored to prepare hydrogels with excellent performance during the last few decades. In this paper, we developed a novel micellar cross-linking copolymerization method without small molecular surfactants to prepare highly stretchable and resilient hydrogels. The polymerization is based on free-radical copolymerization of water soluble acrylamide and a polymerizable macromolecular surfactant (i.e., amphiphilic polyurethane (PU) macromonomer) which can self-assemble into micelles acting as multifunctional cross-linkers. The mechanical properties, such as breaking elongation ratio, modulus and fracture toughness can be easily adjusted by varying the concentration of the polymerizable macromolecular surfactants. In addition, the mechanical energy storage efficiency (also known as resilience) is more than 96% at a strain up to 400%. The high resilience of the obtained hydrogels is due to the reversible assembly of the hydrogen-bonded hydrophobe, which contributes to the dissipation of the crack energy along the hydrogel sample, inside the micelles within the gel network.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据