期刊
POLYMER CHEMISTRY
卷 4, 期 16, 页码 4322-4325出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py00659j
关键词
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资金
- Ghent University via the Concerted Research Actions [BOF11/GOA/023]
- Basic Science Research Program through the National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology [2010-0021839]
- University of Incheon (International Cooperative) Research Grant
- China Scholarship Council [2010629042]
- Ghent University [BOF11/CHN/009]
- National Research Foundation of Korea [2010-0021839] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
This article describes a new class of triple thermoresponsive 'schizophrenic' diblock copolymer that undergoes transitions from conventional micelles (or vesicles) via unimers to reverse micelles (or vesicles) and finally to a precipitated state upon heating. The various transition temperatures of this copolymer could be well controlled by the concentration of trivalent anion and pH that control the upper critical solution temperature of the poly(dimethylaminoethyl methacrtylate) (PDMAEMA) block or the type of poly(methoxy oligo-ethylenegylol methacrylate) (PmOEGA) to vary the lower critical solution temperature.
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