期刊
POLYMER CHEMISTRY
卷 4, 期 16, 页码 4303-4307出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py00562c
关键词
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资金
- European Commission
- Region Wallonne FEDER program through the SMARTFILM project within the Revetements Fonctionnels platform
- Interuniversity Attraction Pole program of the Belgian Federal Science Policy Office [PAI 7/05]
- SOLWATT program (SUNTUBE project)
- OPTI2MAT program of excellence of Region Wallonne
- FNRS-FRFC
- FRIA
- FRS-FNRS
The synthesis of poly[(4,4'-(dihexyl)dithieno(3,2-b;2',3'-d)silole)] has been carried out through Kumada catalyst transfer polycondensation and its copolymerization with 3-hexylthiophene (3HT) leads to well-defined diblock copolymers in terms of molecular characteristics. These copolymers show a wider absorption window than P3HT, which is of potential interest for photovoltaic applications.
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