期刊
POLYMER CHEMISTRY
卷 4, 期 9, 页码 2767-2772出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py00201b
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资金
- National Natural Science Foundation of China [91027006, 21125417]
- Fundamental Research Funds for the Central Universities [2012QNA3013]
- Zhejiang Provincial Natural Science Foundation of China [R4100009]
- Open Project of State Key Laboratory of Supramolecular Structure and Materials
A water-soluble supramolecular polymer has been constructed from self-assembly of a heteroditopic monomer. It shows redox-responsiveness in the presence of a molecular chaperone. Furthermore, this supramolecular polymer material is shape-persistent and free-standing, which can be easily processed into various shapes. These unique features are all due to the dynamically reversible host-guest complexation and good mechanical properties of this supramolecular polymer, making it a platform to construct advanced and sophisticated materials. The formation of the supramolecular polymer was characterized by various techniques including two-dimensional diffusion-ordered NMR, scanning electron microscopy, and viscosity and rheology measurements.
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