期刊
POLYMER CHEMISTRY
卷 3, 期 7, 页码 1680-1692出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1py00446h
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资金
- Agence Nationale de la Recherche (ANR) [ANR-10-BLAN-0932-01]
- Agence Nationale de la Recherche (ANR) [ANR-10-BLAN-0932] Funding Source: Agence Nationale de la Recherche (ANR)
Although they have been known for decades, the synthesis and polymerization of vinyl-1,2,3-triazoles have recently gained attention driven by the spectacular development of the copper-catalyzed azide-alkyne cycloaddition, the most widely applied example of the click chemistry philosophy. Indeed, a broad library of vinyl-1,2,3-triazole-based monomers and polymers carrying aliphatic, aromatic, heterocyclic or functional groups has been reported so far. However, their polymerization has been scarcely reported and is subjected to a broad development in the near future. This review describes the synthesis and polymerization of vinyl-1,2,3-triazole regioisomers with respect to emerging highly efficient, robust and orthogonal chemistries as well as properties of the resulting materials and their potential for the design of smart and stimuli-responsive macromolecular objects.
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