期刊
POLYMER CHEMISTRY
卷 2, 期 8, 页码 1597-1610出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1py00058f
关键词
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资金
- Grants-in-Aid for Scientific Research [23750034] Funding Source: KAKEN
Several recent efforts concerning post-metallocene Group 4 metal complexes incorporating mixed donor [OSSO]-type tetradentate bis(phenolato) ligands are reviewed. These [OSSO]-type ligands can be mainly classified as 5-5-5, 5-6-5 and 6-5-6 arrays of chelate rings toward central metals. As the main topics are described the design and unique coordination chemistry of the [OSSO]-type ligands and catalytic activities of the resultant titanium, zirconium, and hafnium complexes as single-site catalysts for polymerizations and copolymerizations of olefins.
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