期刊
POLYMER
卷 55, 期 1, 页码 304-320出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2013.08.068
关键词
Porous polymers; Emulsion templating; PolyHIPEs
资金
- Israel Science Foundation
- German-Israeli Foundation for Scientific Research and Development
- United States - Israel Binational Science Foundation
- Grand Technion Energy Program
- Russell Berrie Nanotechnology Institute
- Grand Water Research Institute
- Technion VPR Fund
PolyHIPEs are porous emulsion-templated polymers synthesized within high internal phase emulsions (HIPEs). HIPEs are highly viscous, paste-like emulsions in which the major, internal phase, usually defined as constituting more than 74% of the volume, is dispersed as discrete droplets within the continuous, minor, external phase. The surge in polyHIPE research and development parallels that of porous polymers in general and reflects the increasing number of potential applications (reaction supports, separation membranes, tissue engineering scaffolds, controlled release matrices, responsive and smart materials, and templates for porous ceramics and porous carbons). This review focuses upon the research and development in polyHIPEs through the prism of the work in our laboratory. The review includes an overview of the developments in polymerization chemistry, in the types of monomers, in the types of stabilization, in the generation of more complex polyHIPE-based systems (e.g. interpenetrating polymer networks, hybrids, bicontinuous polymers), and in unusual materials systems such as water-retaining polyHIPEs and shape-memory polyHIPEs. (C) 2013 Elsevier Ltd. All rights reserved.
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