期刊
POLYMER
卷 54, 期 23, 页码 6357-6362出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2013.09.040
关键词
Carbon dioxide; Copolymerization; Epichlorohydrin
资金
- National Science Foundation of the People's Republic of China [21074106, 21274123]
- Science and Technology Plan of Zhejiang Province [2010C31036]
Epichlorohydrin (ECH), as a cheap raw chemical material, is an ideal monomer for copolymerization with CO2 to produce biodegradable polycarbonates. This work describes the selective ECH-CO2 copolymerization via heterogeneous catalysis of nanolamellar zinc cobalt double metal cyanide complex (Zn-Co (III) DMCC), affording a poly(carbonate-co-ether) with carbonate content up to 70.7%. Remarkably, the cyclic carbonate contents in the product are 5.0%-11.3% at 25-60 degrees C, better than those from homogeneous catalysis. Moreover, the copolymer with 70.7% carbonate content presents high thermal decomposition temperature of 250 degrees C and relatively high glass-transition temperature (T-g) of 31.2 degrees C. (C) 2013 Elsevier Ltd. All rights reserved.
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