期刊
POLYMER
卷 54, 期 17, 页码 4404-4421出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2013.04.066
关键词
Orientation-induced; Polypropylene; Crystallization
资金
- National Natural Science Foundation of China [50833006, 21274009, 51221002, 50973008]
In polymer processing operations, the molten polymer chains are frequently subjected to shear or/and elongation flow fields, which will produce molecular chain orientation of the melt. This leads to the orientation-induced crystallization has been an important subject in the field of polymer physics. Systematic studies indicated that the chain orientation influences the crystallization kinetics, the final morphology as well as the polymorphic behavior of the polymers. In this article, the effects of pre-orientation on the crystallization of isotactic polypropylene (iPP) concerning the above mentioned aspects have been reviewed. In particular, the formation mechanism of orientation-induced beta-iPP crystallization has been discussed according to the recent experimental results. It is suggested that the local order of the macromolecular chain segments in the melt is most important for beta-nucleation of iPP. The formation of beta-iPP nuclei may be restricted in a certain chain orientation window of the iPP melts. Chain orientation outside of this window results in the formation of alpha-iPP. (c) 2013 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据