期刊
POLYMER
卷 53, 期 10, 页码 2015-2022出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2012.03.019
关键词
Magnetic polymer core/shell colloids; Emulsifier-free emulsion polymerization; High magnetization
资金
- National Nanotechnology Center, National Nanotechnology Center, National Science and Development Agency Nanotechnology Center, Thailand
- Thailand Research Fund (TRF)
- PERCH-CIC
A facile synthetic route for the preparation of magnetic poly(methyl methacrylate) (PMMA) core/polyethyleneimine (PEI) shell colloidal particles, possessing high saturation magnetization is reported. Bilayer oleic acid-stabilized iron oxide nanoparticles (bIOs) were designed to have both favorable encapsulation of iron oxide nanoparticles and interaction with protonated amine groups of PEI. The prepared particles had diameter ranging from 180 to 207 nm with narrow size distribution and displayed highly positive surface charges up to +47 mV. TEM revealed that the well-defined bIOs were successfully encapsulated inside the polymer core-shell colloids. Thermogravimetric analysis and magnetization study indicated that these colloidal particles had the magnetic material up to 80 wt % loading and exhibited superparamagnetic property with high saturation magnetization. Thus, they could be potentially useful in various applications, including magnetic separation, medical diagnostics, or drug delivery. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.
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