期刊
POLYMER
卷 51, 期 23, 页码 5294-5303出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2010.09.022
关键词
Suzuki-polycondensation; Nitroxide-mediated radical polymerization; Block copolymers; pi-Conjugated segments
资金
- Fonds der Chemischen Industrie
- DFG [SFB 287]
- DAAD
The synthesis of pi-conjugated Nitroxide-Mediated Radical Polymerization (NMRP)-macroinitiators by Suzuki-polycondensation in a one-step reaction has been investigated using conventional and microwave-heating in presence of a suitable terminating agent. Alkoxyamine-functionalized poly(para-phenylene)s were initially synthesized by Suzuki-polycondensation and then its block copolymer with styrene by NMRP. Molecular weight and molecular weight distribution of the polymers have been determined in SEC-measurements, while end-group determination was performed with MALDI-ToF-MS. Thin-layer-morphologies of the block copolymers were investigated using tapping-mode AFM. (C) 2010 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据