期刊
POLYMER
卷 50, 期 21, 页码 5142-5148出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2009.09.010
关键词
Solvent size effect; Radius of gyration; Diffusion coefficient
资金
- National Natural Science Foundation of China [20574070, 20674086, 20534020, 50873098, 20734003, 20734006]
- Fund for Creative Research Groups [50621302]
- JLSTP [20070113]
The static and dynamic properties of polymer chains in athermal solvents with different sizes are studied by molecular dynamics method. With increasing solvent size, the radius of gyration and the diffusion coefficient of the polymer decay fast until a critical solvent size is reached. For the polymer diffusion coefficients, this decay only depends on the solvent size; while for the radius of gyration of polymers, this decay depends on both solvent size and the length of the polymers. The increase of solvent size also makes the polymer tend to be thicker ellipsoid until a critical solvent size is reached. The static scaling exponent of the polymer also shows the solvent size dependence. Moreover, four regions are identified where the polymers show different dynamic behaviors according to the dynamic structure factors of the polymer. (C) 2009 Elsevier Ltd. All rights reserved.
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