期刊
POLYMER
卷 50, 期 25, 页码 5928-5932出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2009.10.030
关键词
RAFT polymerization; Thiol-ene click reaction; Branched polymer
资金
- ARC
A vinyl functional polymer, viz, poly(vinyloxyethyl methacrylate) (poly(VEMA) was synthesized by the RAFT polymerization of an asymmetric divinyl monomer, VEMA. This polymer, with pendant vinyloxyl groups, was subsequently reacted with three thiol compounds; 2-mercaptoethanol, cysteamine and 3-mercaptoproponic acid via the thiol-ene reactions. The resulting branched polymers contained hydroxyl, amino and carboxylic acid functionalities suitable for further reactions and conjugations. (C) 2009 Elsevier Ltd. All rights reserved.
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