期刊
POLYMER
卷 50, 期 1, 页码 42-49出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2008.10.050
关键词
Polymer-clay nanocomposite; Reversible addition-fragmentation chain transfer; Miniemulsion
RAFT-mediated random poly(styrene-co-butyl acryl ate)-[N-(4-((((dodecylthio)-carhonothioyl)thio)methyl)benzyl)-N,N-dimethylethanammonium]-clay nanocomposites (P(S-co-BA)-DCTBAB-PCNs) and poly(styrene-co-butyl acrylate)-[N,N-dimethyl-N-(4-(((phenylcarbonothioyl)thio)-methyl)benzyl)ethanammonium]-clay nanocomposites (P(S-co-BA)-PCDBAB-PCNs) were prepared by miniemulsion free-radical polymerization. The RAFT agents (i.e. DCTBAB and PCDBAB) were anchored onto the clay layers prior to polymerization, and were able to control the polymerization process, as evident from the decreasing molar mass and polydispersity index (PDI) values as the concentration of the RAFT agent in the system increased. The efficiency of the anchored RAFT agents increased as the RAFT agent concentration in the system increased, i.e. as the clay loading increased. The nanocomposites that were prepared were found to have a partially exfoliated morphology at low clay loadings, as determined by SAXS and TEM, whereas, at high clay loadings the morphology changed to become predominantly intercalated. The thermo-mechanical properties of the nanocomposites were found to be a function of the molar mass, PDI, PCN morphology, and clay loading. In the glassy state, the storage modulus was seen to effectively decrease as clay loading increased, whereas the opposite was true for the loss modulus and tan delta. At low clay loadings the melt theological properties were dominated by the matrix effects, whereas at high clay loadings the effect of the clay filler dominated, resulting in pseudo solid-liquid-like behavior. (C) 2008 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据