Nascent morphology of syndiotactic polystyrene synthesized over silica-supported metallocene catalyst

The nascent morphology of semi-crystalline syndiotactic polystyrene (sPS) polymerized over silica-supported pentamethyl cyclopentadienyl titanium trimethoxide (Cp*Ti(OCH3)(3)) catalyst in a liquid slurry polymerization has been investigated under various reaction conditions. The scanning electron microscopic analysis of nascent polymers reveals that sPS molecules grow as long nanofibrils of 30-50 nm diameter and X-ray diffraction analysis shows the co-crystalline phases including both sPS and low molecular weight guest molecules of monomer and diluent. The energy dispersive X-ray spectroscopy also shows that the disintegration of silica primary particles occurs during the polymerization as evidenced by the uniform dispersion of silicon and aluminum in a polymer particle. The fibrous growth of the polymer inside a polymer particle leads to the shape replication of the original silica particles. (C) 2008 Elsevier Ltd. All rights reserved.