期刊
POLYHEDRON
卷 154, 期 -, 页码 357-363出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2018.08.002
关键词
HKUST-1; MOF-199; Gold nanoparticles; Microwave synthesis; Phase transition
资金
- Ministry of Education and Science of Russia [16.3871.2017/4.6]
We report a two-step room temperature protocol for functionalization of copper-based metal-organic framework MOF-199, also known as HKUST-1, with gold nanoparticles. The resulted material is characterized with XRD, TEM, BET, UV-Vis and FTIR techniques building up a complete picture of its structural, electronic and vibrational properties. We also found, that the presence of gold induces a partial phase transformation of MOF under microwave heating, leading to formation of [Cu-2(OH)(BTC)(H2O)](n) material with one-dimensional channels. (C) 2018 Elsevier Ltd. All rights reserved.
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