Physicochemical properties of zinc monoamino phthalocyanine conjugated to folic acid and single walled carbon nanotubes

This study reports on the photophysical and photochemical behavior of the conjugates formed by covalent and non-covalent bonding between zinc monoamino phthalocyanine (ZnMAPc) and either single walled carbon nanotubes (SWCNTs) or folic acid (FA). The conjugates were characterized using FTIR, X-ray powder diffractometry, thermogravimetric analyses, transmission electron microscopy and Raman spectroscopy. H-1 NMR and mass spectroscopies were only employed for ZnMAPc-FA conjugate. There was a slight increase in the triplet and singlet oxygen quantum yields on conjugating ZnMAPc to SWCNTs (or FA), while a decrease in the photophysical and photochemical parameters were observed upon adsorption of the ZnMAPc-FA conjugate to SWCNTs. (C) 2013 Elsevier Ltd. All rights reserved.