期刊
POLYHEDRON
卷 30, 期 18, 页码 3127-3130出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2011.03.008
关键词
Spin crossover; Ligand-driven light-induced spin change; High pressure
资金
- Grants-in-Aid for Scientific Research [23750056, 22350057] Funding Source: KAKEN
Toward the realization of a ligand-driven light-induced spin change (LD-LISC) around room temperature, we have investigated the spin-crossover phenomenon in [Fe(stpy)(4)(X)(2)] (stpy = styrylpyridine, X = NCS, NCBH3) under high pressure. The spin transition temperature increases from 110 to 220 K with increasing applied pressure up to 0.75 GPa for [Fe(trans-stpy)(4)(NCS)(2)], while [Fe(cis-stpy)(4)(NCS)(2)] shows the high-spin state in the temperature region between 2 and 300 K even at 0.75 GPa. In the case of X = NCBH3, due to the stronger ligand field of NCBH3, the spin transition temperature increases from 240 to 360 K with increasing applied pressure up to 0.50 GPa for [Fe(trans-stpy)(4)(NCBH3)(2)]. In the case of [Fe(cis-stpy)(4)(NCBH3)(2)], the spin state is the high-spin state in the temperature region between 2 and 300 K. However, the spin transition appears at 125 K under 0.5 GPa and the transition temperature increases with increasing applied pressure. In this way, we have decided the applied pressure region of 0.65-1.09 GPa where [Fe(stpy)(4)(NCBH3)(2)] undergoes LD-LISC at room temperature. (C) 2011 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据