期刊
POLYHEDRON
卷 29, 期 11, 页码 2291-2296出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2010.04.035
关键词
Schiff-base ligand; Transition-metal coordination compound; X-ray crystallography; Oxidation catalysis; ESI-MS
资金
- NIOK, HRSMC, PTN
- Spanish CSIC
- Spanish Ministerio de Ciencia y Innovacion [16-01-723]
Four coordination compounds were synthesized in high yields from different transition metal ions (Fe-III, Co-II, and Cu-II) and an in situ generated Schiff-base ligand, i.e. 2-methoxy-6-((quinolin-8-ylimino) methyl)phenol (mqmpH). The compounds were characterized by single-crystal X-ray diffraction, ESI-MS. IR spectroscopy, and ligand-field spectroscopy. The iron(III) complex is an efficient catalyst for the oxidation of alkanes and alkenes, under relatively mild conditions and with dihydrogen peroxide as terminal oxidant. (C) 2010 Elsevier Ltd. All rights reserved.
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