期刊
POLYHEDRON
卷 29, 期 1, 页码 30-33出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2009.05.067
关键词
N-heterocyclic carbene; Rhodium; Copper; Coordination chemistry
资金
- CNRS
- UdS
5,7-Di-tert-butyl-3-phenyl benzoxazolium tetra fluoroborate 1 could be prepared by simple reaction of the corresponding aminophenol with triethyl orthoformate under acidic conditions. Both rhodium(I) and copper(I) complexes with benzoxazol-2-ylidene ligand were then efficiently synthesised in a straightforward and smooth manner involving the reaction of benzoxazolium salt 1 with metal precursor and an external base. The complexes have been fully characterised and used in metal-catalysed hydrosilylation of ketones, where they showed poor catalytic activity, presumably due to low stability of the complexes under those conditions. (C) 2009 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据