Synthesis of oleylamine capped copper nanocrystals via thermal reduction of a new precursor

The present investigation reports the novel synthesis of copper nanocrystals using thermal reduction, and their physicochemical characterization. The copper nanocrystal powder has been prepared using [bis(2-hydroxyacetophenato)copper(II)] as a precursor. The effect of oleylamine and triphenylphosphine on the particle morphology has been investigated. Transmission electron microscopy (TEM) analysis has demonstrated that the copper nanocrystals have an average diameter of about 3 nm. The as-prepared copper nanocrystals were characterized by XRD, SEM, TEM, EDX. UV-Vis and FTIR. (C) 2008 Elsevier Ltd. All rights reserved.