期刊
POLYCYCLIC AROMATIC COMPOUNDS
卷 30, 期 5, 页码 260-273出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10406638.2010.524851
关键词
aryl radicals; carbene; Flash Vacuum Pyrolysis (FVP); PAH; reaction mechanism
资金
- Department of Energy
Phenanthrene, the archetypal obay regiono polycyclic aromatic hydrocarbon (PAH), loses two hydrogen atoms when subjected to flash vacuum pyrolysis (FVP) at 1100 degrees C and suffers a major skeletal rearrangement to form pyracylene (1), along with 1-, 3-, and 4-ethynylacenaphthylene (2, 3, and 4, respectively). Evidence is presented that implicates cyclopenta[bc]acenaphthylene (7) as a key intermediate on the reaction pathway from phenanthrene to these four C14H8 products.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据