期刊
CRYSTALLOGRAPHY REVIEWS
卷 21, 期 3, 页码 160-212出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/0889311X.2014.964229
关键词
polymorphism; database; metal complexes; hydrogen bonding; amino acid; crystal structure
After the discovery of X-ray diffraction by crystals, amino acids were among the first organic compounds to have their solid-state structures investigated. The Cambridge Structural Database now contains more than 3500 entries for alpha-amino acids alone. After a short introduction dealing with the early history of X-ray structure determination, this review provides a classification of amino acid structures, describes essential structural elements, especially hydrogen bonding preferences and coordination to metal ions, and considers recent investigations on phase transitions as the result of extreme temperatures or pressure.
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