期刊
CHEMICAL SCIENCE
卷 6, 期 7, 页码 3757-3764出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc00718f
关键词
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资金
- Ministerio de Economia y Competitividad, Spain [CTQ2012-31611, CTQ2014-58812-C2-2-R]
- Junta de Castilla y Leon
- Obra Social la Caixa [OSLC-2012-007]
- European Commission [FP7-SEC-2012-312411]
- Consejeria de Educacion y Cultura y Fondo Social Europeo [BU246A12-1]
- Fondo Social Europeo
- Ministerio de Economia y Competitividad
Selected new fluorogenic probes that interact in different ways with Hg2+ and MeHg+ have been prepared and used for the chemical speciation of both cations in aqueous solution as well as in HEK293 cells. The best selective speciation of Hg2+ and MeHg+ has been achieved by in vitro approaches based on fluorogenic probes supported in cultured cells, due to the particular sensitivity of the HEK293 cells to permeation by Hg2+, MeHg+ and the fluorogenic probes. In particular, MeHg+ was selectively detected in cell nuclei by probe JG45.
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