期刊
CHEMICAL SCIENCE
卷 6, 期 8, 页码 4993-4999出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc01251a
关键词
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资金
- National Natural Science Foundation of China [21177037, 21277045, 21322307]
- Public welfare project of the Ministry of Environmental Protection [201309021]
- Shu Guang project of the Shanghai Municipal Education Commission
- Shanghai Education Development Foundation
- Fundamental Research Funds for the Central Universities
The oxygen evolution reaction (OER) has been regarded as a key half reaction for energy conversion technologies and requires high energy to create O=O bonds. Transition metal oxides (TMOs) seem to be a promising and appealing solution to the challenge because of the diversity of their d-orbital states. We chose IrO2 as a model because it is universally accepted as a current state-of-the-art OER catalyst. In this study, copper-doped IrO2, particularly Cu0.3Ir0.7O delta, is shown to significantly improve the OER activity in acidic, neutral and basic solutions compared to un-doped IrO2. The substituted amount of Cu in IrO2 has a limit described by the Cu0.3Ir0.7O delta composition. We determined that the performance of Cu0.3Ir0.7O delta is due primarily to an increase in the Jahn-Teller effect in the CuO6 octahedra, and partially to oxygen defects in the lattice induced by the IrO6 octahedral geometric structure distortions, which enhance the lift degeneracy of the t(2g) and e(g) orbitals, making the d(z)(2) orbital partially occupied. This phenomenon efficiently reduces the difference between Delta G2 and Delta G3 in the free energy from the density functional theoretical (DFT) calculations and can yield a lower theoretical overpotential comparable to that of IrO2. The proposed method of doping with foreign elements to tune the electron occupation between the t(2g) and e(g) orbital states of Ir creates an opportunity for designing effective OER catalysts using the TMO groups.
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