期刊
CHEMICAL SCIENCE
卷 6, 期 4, 页码 2323-2327出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc00024f
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资金
- Labex CHARMMMAT
- ANR
- French Infrastructure for Integrated Structural Biology (FRISBI) [ANR-10-INSB-05-01]
- EU-COST Actions [CM1003]
- Perspect-H2O
In the present work we describe the synthesis and study of a Ru-II-Fe-II chromophore-catalyst assembly designed to perform the light-induced activation of an iron bound water molecule and subsequent photo-driven oxidation of a substrate. Using a series of spectroscopic techniques, we demonstrate that excitation of the chromophore unit with 450 nm light, in the presence of a sacrificial electron acceptor, triggers a cascade of electron transfers leading to the formation of a high valent iron(IV)-oxo center from an iron(II)-bound water molecule. The activity of this catalytic center is illustrated by the oxidation of triphenyl phosphine.
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