期刊
CHEMICAL SCIENCE
卷 6, 期 5, 页码 2843-2852出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc03942d
关键词
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资金
- European Research Council [267816]
- Swiss National Science Foundation
- University of Basel
- European Community [314068, 316906]
- Spanish Ministry of Economy and Competitiveness (MINECO) [MAT2011-24594]
- Generalitat Valenciana [Prometeo/2012/053]
A series of cyclometalated iridium(III) complexes [Ir(C<^>N) 2(N<^>N)][PF6] (N<^>N = 2,2'-bipyridine (1), 6-phenyl-2,2'-bipyridine (2), 4,4'-di-tert-butyl-2,2'-bipyridine (3), 4,4'-di-tert-butyl-6-phenyl-2,2'-bipyridine (4); HC<^>N = 2-(3-phenyl) phenylpyridine (HPhppy) or 2-(3,5-diphenyl) phenylpyridine (HPh(2)ppy)) are reported. They have been synthesized using solvento precursors so as to avoid the use of chlorido-dimer intermediates, chloride ion contaminant being detrimental to the performance of [Ir(C<^>N) 2(N<^>N)][ PF6] emitters in light-electrochemical cell (LEC) devices. Single crystal structure determinations and variable temperature solution H-1 NMR spectroscopic data confirm that the pendant phenyl domains engage in multiple face-to-face pi-interactions within the coordination sphere of the iridium(III) centre. The series of [Ir(Phppy)(2)(N<^>N)](+) and [Ir(Ph(2)ppy)(2)(N<^>N)](+) complexes investigated include those with and without intra-cation face-to-face pi-stacking. All the complexes display excellent luminescent properties, in particular when employed in thin solid films. The most important observation is that all the LECs using the [Ir(Phppy)(2)(N<^>N)](+) and [Ir(Ph(2)ppy)(2)(N<^>N)](+) emitters (i.e. with and without intra-cation pi-stacking interactions) exhibit very stable luminance outputs over time, even when driven at elevated current densities. The most stable LEC had an extrapolated lifetime of more than 2500 hours under accelerated testing conditions.
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