期刊
CHEMICAL SCIENCE
卷 6, 期 4, 页码 2354-2359出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc03849e
关键词
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资金
- CREST, JST
- Japan Society for the Promotion of Science (JSPS)
- [24109007]
- [25109543]
- Grants-in-Aid for Scientific Research [24750038, 25109543, 24109007] Funding Source: KAKEN
A reproducible formation of strongly bent crystals was accomplished by structurally restraining macrocyclic pi-conjugated molecules. The model pi-units consist of two 9,10-bis(2-thienylethynyl)anthracenes with a strong propensity for stacking, which are connected in a macrocyclic fashion via two alkylene linkers. The correlation between the crystalline morphology and the macrocyclic structures restrained by a variety of flexible alkylene linker combinations was systematically studied. Bent crystals were obtained only with specific alkylene linkers of appropriate chain length. The alkylene linkers can adopt different conformations in the crystal packing, so as to fill voids within the macrocycle. The ability to form several similar molecular structures with different alkylene conformations gives rise to contaminations of different crystalline phases within a single crystal, and it is these phase contaminations which are responsible for the bending of the crystals.
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