期刊
CHEMICAL SCIENCE
卷 6, 期 7, 页码 4179-4183出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc00494b
关键词
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资金
- National Basic Research Program of China (973 Program) [2015CB856600]
- National Natural Science Foundation of China [21332009, 21421091, 21361140373]
- Chinese Academy of Sciences
An organocatalytic asymmetric chlorinative dearomatization of naphthols was realized for the first time, providing chiral naphthalenones with a Cl-containing all-substituted stereocenter in excellent yields and enantioselectivity (up to 97% yield and 96% ee). The reaction features mild reaction conditions, good tolerance of diverse functional groups and simple reaction operation.
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