期刊
CHEMICAL SCIENCE
卷 6, 期 6, 页码 3393-3401出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc00449g
关键词
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资金
- Swiss National Science Foundation [200020-129501, 200020-140298]
- CNRS
- University of Strasbourg
- US National Science Foundation [DMR-1066116, DMR-1120901, OISE-1243313]
- Humboldt Foundation
- P. Roy Vagelos Chair at the University of Pennsylvania
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1066116] Funding Source: National Science Foundation
- Swiss National Science Foundation (SNF) [200020_140298, 200020_129501] Funding Source: Swiss National Science Foundation (SNF)
Twelve chiral and achiral self-assembling dendrons have been grafted onto a [60] fullerene hexa-adduct core by copper-catalyzed alkyne azide click cycloaddition. The structure adopted by these compounds was determined by the self-assembling peripheral dendrons. These twelve dendrons mediate the self-organisation of the dendronized [60] fullerene into a disc-shaped structure containing the [60] fullerene in the centre. The fullerene-containing discs self-organise into helical supramolecular columns with a fullerene nanowire-like core, forming a 2D columnar hexagonal periodic array. These unprecedented supramolecular structures and their assemblies are expected to provide new developments in chiral complex molecular systems and their application to organic electronics and solar cells.
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