期刊
PHYSICS OF THE SOLID STATE
卷 51, 期 5, 页码 966-969出版社
PLEIADES PUBLISHING INC
DOI: 10.1134/S1063783409050138
关键词
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资金
- Federal Agency for Science and Innovation [MK-4278.2008.2]
Ludwigite single crystals of compositions Co3O2BO3 and Co3 - x Fe (x) O2BO3 (x a parts per thousand 0.14) have been synthesized. The crystal structure is investigated at room temperature, and the magnetization is studied in the temperature range T = 4.2-100 K in magnetic fields of up to 600 Oe. The orthorhombic symmetry is revealed, and the unit cell parameters are determined. A number of features are established for the temperature dependence of the magnetization. In unsubstituted Co3O2BO3, two magnetic transitions are found at T (C1) = 43 K and T (C2) = 15 K. At temperatures below 40 K, spin-glass state is revealed. Substitution of iron ions for cobalt ions leads to a noticeable shift in the magnetic transitions toward the high-temperature range: T (C1) = 83 K and T (C2) = 74 K. A ferromagnetic ordering of the P type is found in the Co3 - x Fe (x) O2BO3 (x a parts per thousand 0.14) compound.
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