期刊
PHYSICS AND CHEMISTRY OF MINERALS
卷 41, 期 7, 页码 527-535出版社
SPRINGER
DOI: 10.1007/s00269-014-0664-2
关键词
Ruby; High-pressure; Radial X-ray diffraction; Strength
资金
- National Natural Science Foundation of China [11027405, 10976018]
- China 973 Program [2011CB808200]
- Carnegie-DOE Alliance Center
- U.S. National Science Foundation
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-98CH10886]
Polycrystalline ruby (alpha-Al2O3:Cr3+), a widely used pressure calibrant in high-pressure experiments, was compressed to 68.1 GPa at room temperature under non-hydrostatic conditions in a diamond anvil cell. Angle-dispersive X-ray diffraction experiments in a radial geometry were conducted at beamline X17C of the National Synchrotron Light Source. The stress state of ruby at high pressure and room temperature was analyzed based on the measured lattice strain. The differential stress of ruby increases with pressure from similar to 3.4 % of the shear modulus at 18.5 GPa to similar to 6.5 % at 68.1 GPa. The polycrystalline ruby sample can support a maximum differential stress of similar to 16 GPa at 68.1 GPa under non-hydrostatic compression. The results of this study provide a better understanding of the mechanical properties of this important material for high-pressure science. From a synthesis of existing data for strong ceramic materials, we find that the high-pressure yield strength correlates well with the ambient pressure Vickers hardness.
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