Critical Doping for the Onset of a Two-Band Superconducting Ground State in SrTiO3-δ

In doped SrTiO3 superconductivity persists down to an exceptionally low concentration of mobile electrons. This restricts the relevant energy window and possible pairing scenarios. We present a study of quantum oscillations and superconducting transition temperature T-c as the carrier density is tuned from 10(17) to 10(20) cm(-3) and identify two critical doping levels corresponding to the filling thresholds of the upper bands. At the first critical doping, which separates the single-band and the two-band superconducting regimes in oxygen-deficient samples, the steady increase of T-c with carrier concentration suddenly stops. Near this doping level, the energy dispersion in the lowest band displays a downward deviation from parabolic behavior. The results impose new constraints for microscopic pairing scenarios.