4.8 Article

Persistent Photoconductivity in Strontium Titanate

期刊

PHYSICAL REVIEW LETTERS
卷 111, 期 18, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.111.187403

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资金

  1. NSF [DMR-1004804, DMR-1066772]
  2. DOE [DE-FG02-07ER46386]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Materials Research [1004804] Funding Source: National Science Foundation
  5. Division Of Materials Research
  6. Direct For Mathematical & Physical Scien [1359523] Funding Source: National Science Foundation

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Persistent photoconductivity was observed in strontium titanate (SrTiO3) single crystals. When exposed to sub-bandgap light (2.9 eV or higher) at room temperature, the free-electron concentration increases by over 2 orders of magnitude. After the light is turned off, the enhanced conductivity persists for several days, with negligible decay. From positron lifetime measurements, the persistent photoconductivity is attributed to the excitation of an electron from a titanium vacancy defect into the conduction band, with a very low recapture rate.

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