Magnetic Self-Organized Atomic Laminate from First Principles and Thin Film Synthesis

The first experimental realization of a magnetic M(n+1)AX(n) (MAX) phase, (Cr0.75Mn0.25)(2)GeC, is presented, synthesized as a heteroepitaxial single crystal thin film, exhibiting excellent structural quality. This self-organized atomic laminate is based on the well-known Cr2GeC, with Mn, a new element in MAX phase research, substituting Cr. The compound was predicted using first-principles calculations, from which a variety of magnetic behavior is envisaged, depending on the Mn concentration and Cr/Mn atomic configuration within the sublattice. The analyzed thin films display a magnetic signal at room temperature.