4-Methoxyanilinium Perrhenate 18-Crown-6: A New Ferroelectric with Order Originating in Swinglike Motion Slowing Down

A supramolecular adduct 4-methoxyanilinium perrhenate 18-crown-6 was synthesized, which under-goes a disorder-order structural phase transition at about 153 K (T-c) due to slowing down of a pendulumlike motion of the 4-methoxyanilinium group upon cooling. Ferroelectric hysteresis loop measurements give a spontaneous polarization of 1: 2 mu C/cm(2). Temperature-dependent solid-state nuclear magnetic resonance measurements reveal three kinds of molecular motions existing in the compound: pendulumlike swing of 4-methoxyanilinium cation, rotation of 18-crown-6 ring, and rotation of the methoxyl group. When the temperature decreases, the first two motions are frozen at about 153 K and the methoxyl group becomes rigid at around 126 K. The slowing down or freezing of pendulumlike motion of the cation triggered by temperature decreasing corresponds to the centrosymmetric-to-noncentrosymmetric arrangement of the compound, resulting in the formation of ferroelectricity.