期刊
PHYSICAL REVIEW LETTERS
卷 110, 期 19, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.110.196403
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资金
- Swiss NSF [PA00P2-136420]
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- Swiss National Science Foundation (SNF) [PA00P2_136420] Funding Source: Swiss National Science Foundation (SNF)
Oxygen vacancies created in anatase TiO2 by UV photons (80-130 eV) provide an effective electron-doping mechanism and induce a hitherto unobserved dispersive metallic state. Angle resolved photoemission reveals that the quasiparticles are large polarons. These results indicate that anatase can be tuned from an insulator to a polaron gas to a weakly correlated metal as a function of doping and clarify the nature of conductivity in this material.
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