期刊
PHYSICAL REVIEW LETTERS
卷 110, 期 23, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.110.236102
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资金
- Materials Science and Engineering Division, Office of Basic Energy Sciences, U.S. Department of Energy
- Scientific User Facility Division, Office of Basic Energy Sciences, U.S. Department of Energy
- Oak Ridge Institute for Science and Education
- Oak Ridge Associated University
Quasielastic neutron scattering of H-2 and D-2 in the same nanoporous carbon at 10-40 K demonstrates extreme quantum sieving, with D-2 diffusing up to 76 times faster. D-2 also shows liquidlike diffusion while H-2 exhibits Chudley-Elliott jump diffusion, evidence of their different relationships with the local lattice of adsorption sites due to quantum effects on intermolecular interactions. The onset of diffusion occurs at 22-25 K for H-2 and 10-13 K for D-2. At these temperatures, H-2 and D-2 have identical thermal de Broglie wavelengths that correlate with the dominant pore size.
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