Symmetric and Asymmetric Coalescence of Drops on a Substrate

The coalescence of viscous drops on a substrate is studied experimentally and theoretically. We consider cases where the drops can have different contact angles, leading to a very asymmetric coalescence process. Side view experiments reveal that the bridge'' connecting the drops evolves with self-similar dynamics, providing a new perspective on the coalescence of sessile drops. We show that the universal shape of the bridge is accurately described by similarity solutions of the one-dimensional lubrication equation. Our theory predicts that, once the drops are connected on a microscopic scale, the bridge grows linearly in time with a strong dependence on the contact angles. Without any adjustable parameters, we find quantitative agreement with all experiments.