期刊
PHYSICAL REVIEW LETTERS
卷 108, 期 10, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.108.106801
关键词
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资金
- NSF [DMR-0941645, OCI-1047997]
- DOE [DE-SC0001878]
- National Energy Research Scientific Computing Center (NERSC)
- Texas Advanced Computing Center (TACC) [TG-DMR090026]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0941645] Funding Source: National Science Foundation
- Office of Advanced Cyberinfrastructure (OAC)
- Direct For Computer & Info Scie & Enginr [1047997] Funding Source: National Science Foundation
We study the structure and electronic properties of (TiO2)(2-10) clusters by using basin hopping based on density functional theory, combined with many-body perturbation theory. We show that in photoemission experiments performed on anions isomers with high electron affinity are selectively observed rather than those with the lowest energy. These isomers possess a highly reactive Ti3+ site. The selectivity for highly reactive clusters may be exploited for applications in catalysis.
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