期刊
PHYSICAL REVIEW LETTERS
卷 108, 期 26, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.108.268302
关键词
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资金
- Engineering and Physical Sciences Research Council (EPSRC)
- Leverhulme Trust [EP/G007837/1, ECF/2010/0380, F00/114 BI]
- NANOCAGE FP6 training network
- EPSRC
- University of Nottingham High Performance Computing Facility
- Engineering and Physical Sciences Research Council [EP/G007837/1] Funding Source: researchfish
- EPSRC [EP/G007837/1] Funding Source: UKRI
We show that the precise orientation of a C-60 molecule which terminates the tip of a scanning probe microscope can be determined with atomic precision from submolecular contrast images of the fullerene cage. A comparison of experimental scanning tunneling microscopy data with images simulated using computationally inexpensive Huckel theory provides a robust method of identifying molecular rotation and tilt at the end of the probe microscope tip. Noncontact atomic force microscopy resolves the atoms of the C-60 cage closest to the surface for a range of molecular orientations at tip-sample separations where the molecule-substrate interaction potential is weakly attractive. Measurements of the C-60-C-60 pair potential acquired using a fullerene-terminated tip are in excellent agreement with theoretical predictions based on a pairwise summation of the van der Waals interactions between C atoms in each cage, i.e., the Girifalco potential [L. Girifalco, J. Phys. Chem. 95, 5370 (1991)].
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