Giant Phonon Softening and Enhancement of Superconductivity by Phosphorus Doping of BaNi2As2

The effects of phosphorus doping on the structural and superconducting phase transitions of BaNi2(As1-xPx)(2) were studied. The specific heat, resistivity, and magnetic susceptibility were measured. The results revealed an abrupt increase in the superconducting transition temperature (T-c) from 0.6 K in the triclinic phase (space group P (1) over bar) with less phosphorus (x <= 0.067) to 3.3 K in the tetragonal phase (space group I4/mmm) with more phosphorus (x >= 0.067). Our data analysis suggests that a doping-induced softening related to an in-plane Ni and As(P) phonon mode is responsible for the enhanced superconductivity in the tetragonal phase.