期刊
PHYSICAL REVIEW LETTERS
卷 109, 期 12, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.109.128101
关键词
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资金
- Lundbeck Foundation
- Carlsberg Foundation
- Danish Research Agency
- European Community
- RFBR [11-03-01214]
Photoelectron spectra of the deprotonated green fluorescent protein chromophore have been measured in the gas phase at several wavelengths within and beyond the S-0-S-1 photoabsorption band of the molecule. The vertical detachment energy (VDE) was determined to be 2.68 +/- 0.1 eV. The data show that the first electronically excited state is bound in the Franck-Condon region, and that electron emission proceeds through an indirect (resonant) electron-emission channel within the corresponding absorption band.
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