期刊
PHYSICAL REVIEW LETTERS
卷 106, 期 12, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.106.128301
关键词
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资金
- National Science Foundation (NSF), Division of Material Research [0906425]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0906425] Funding Source: National Science Foundation
We show that thin film star-shaped macromolecules exhibit significant differences in their average vitrification behavior, in both magnitude and thickness dependence, from their linear analogs. This behavior is dictated by a combination of their functionality and arm length. Additionally, the glass transition temperature at the free surface of a star-shaped molecule film may be higher than that of the interior, in contrast to their linear analogs where the opposite is true. These findings have implications for other properties, due largely to the origins, entropic, of this behavior.
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