期刊
PHYSICAL REVIEW LETTERS
卷 106, 期 24, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.106.247802
关键词
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资金
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0847304] Funding Source: National Science Foundation
We study the nematic-smectic phase transition of a thermotropic liquid crystal confined to a spherical shell. Far from the nematic-smectic phase transition temperature, T-NS, we observe a configuration with four +1/2 defects, as predicted by theory. Since in this case K-1 approximate to K-3, the four defects are confined at the thinnest part of the shell to minimize the energy associated with the defect cores. By contrast, near T-NS, where K-3 >> K-1, bend distortions become prohibited and the defects organize themselves along a great circle of the sphere, confirming recent theoretical and simulation results. During this structural change, the defects associate in two pairs that behave independently. In the smectic phase, we observe a new configuration displaying curvature walls.
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