4.8 Article

Scaling Theory for Percolative Charge Transport in Disordered Molecular Semiconductors

期刊

PHYSICAL REVIEW LETTERS
卷 107, 期 13, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.107.136601

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  1. Dutch Polymer Institute (DPI) [680]
  2. STW/NWO [VENI 11166]

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We present a scaling theory for charge transport in disordered molecular semiconductors that extends percolation theory by including bonds with conductances close to the percolating one in the random-resistor network representing charge hopping. A general and compact expression is given for the charge mobility for Miller-Abrahams and Marcus hopping on different lattices with Gaussian energy disorder, with parameters determined from numerically exact results. The charge-concentration dependence is universal. The model-specific temperature dependence can be used to distinguish between the hopping models.

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