Electron-Hole Transitions in Multiply Charged Ions for Precision Laser Spectroscopy and Searching for Variations in α

We consider transitions of electron holes (vacancies in otherwise filled shells of atomic systems) in multiply charged ions that, due to level crossing of the holes, have frequencies within the range of optical atomic clocks. Strong E1 transitions provide options for laser cooling and trapping, while narrow transitions can be used for high-precision spectroscopy and tests of fundamental physics. We show that hole transitions can have extremely high sensitivity to alpha variation and propose candidate transitions that have much larger alpha sensitivities than any previously seen in atomic systems.