期刊
PHYSICAL REVIEW LETTERS
卷 104, 期 13, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.104.135502
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资金
- Swedish Energy Agency [NANO-SEE 181-1]
Using a new indirect nanoplasmonic sensing method with subsecond resolution, we have studied hydriding and dehydriding kinetics of Pd nanoparticles in the size range 1.8-5.4 nm. Strong particle-size effects are observed. The scaling of the hydriding and dehydriding time scales satisfies power and power-exponential laws. The former (with an exponent of 2.9) is in perfect agreement with Monte Carlo simulations of diffusion-controlled hydriding kinetics. The latter is explained by the effect of surface tension on hydrogen desorption from the surface layer. The approach is generalizable to other reactant-nanoparticle systems.
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