Ferroelectric-Paraelectric Transition in BiFeO3: Crystal Structure of the Orthorhombic β Phase

A detailed investigation using variable temperature powder neutron diffraction demonstrates that BiFeO3 undergoes a phase transition from the ferroelectric alpha phase (rhombohedral, R3c) to a paraelectric beta phase (orthorhombic, Pbnm) between 820 degrees C and 830 degrees C. Coexistence of both phases over a finite temperature interval, together with abrupt changes in key structural parameters, confirms that the transition is first order. The beta phase corresponds to a GdFeO3-type perovskite structure.